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The red shift of this peak with respect to bulk Si crystals (521 can1) can be attributed to confinement effects [13, 14].
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These decreases in diameters exhibit a blue shift that was attributed to confinement effects.
This enhanced charge retention should be attributed to charge confinement in Ge-NCs, immunity of Ge-NCs to local defects in the dielectric, and interface traps.
As mentioned above, this PL enhancement is difficult to be attributed to quantum confinement or indirect direct bandgap transition since the mean diameter of the MQW nanorods is much larger than the exciton Bohr radius of Si and Ge.
It has been reported that such a blue shift could be attributed to phonon confinement caused by a decrease in crystal size of anatase [28] or an increased surface strain of TiO2 caused by the adsorption of surfactants [29].
This shift can also be attributed to the confinement of the aggregative sensing assay within pores, a process that can theoretically shift the distribution of aggregates to favor smaller particles in comparison to free solution with a given glucose concentration because of entropy requirements and steric hindrances presented by the pores.
Discussion: The results of this study are consistent with the hypothesis that the selective action of epidurally applied BAB suspension can be attributed to the spatial confinement of active BAB-concentrations within the epidural space.
Emission properties were controlled at 414 441 nm by tailoring their size, and the blue shift of the absorption edges of Fe:ZnSe samples could be attributed to the quantum confinement within the nanocrystals.
This should be attributed to the quantum confinement effect [23].
The much larger PL intensities should be attributed to the effective confinement of carriers in the well layers.
We believe this may be attributed to the exciton confinement in the surrounding interface of the formed nanograins due to the small thickness of the material.
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