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The observed bands can be assigned to electron transitions in the VO4 3− groups; those are constituents of mentioned compounds.
The immobilization of photosynthetic proteins on hematite, in particular C-phycocyanin, yields a substantial increase of the photocurrent density which can be assigned to electron hole pair formation in the protein by light absorption in a wavelength range that exceeds the absorption range of the hematite.
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These data indicate that the faster of the processes observed with the SdhB-Ile209Lys involves electron transfer between the [3Fe 4S] cluster and heme, with the much slower rate (∼47 seen seen with UQ being assigned to electron transfer between the [3Fe 4S] cluster and the quinone.
In addition, the peak at 3.321 eV also appeared in PL of pure ZnO nanowires as shown in Figure 3c, which could be assigned to two-electron satellite (TES) emission, which often appeared in low-temperature PL of ZnO and disappeared at the temperature around 50 K [28].
The Hg2+-induced fluorescence quenching may be assigned to the energy or electron transfer from emissive aza-BODIPY core to Hg2+.
From calculations of rate transitions, the two main peaks in MPL spectra can be assigned to transitions between ground electron and heavy hole states.
This could be assigned to an inhibition of the electron transfer reactions at the front of de-adhesion and an increased adhesion force between polymer film and oxide covered metal preventing the formation of an extended interfacial electrolyte layer.
The strong emission peak around 421 nm (2.94 eV) can be assigned to the recombination of an electron at zinc interstitial (Zni) and a hole in the valence band [36].
The reason of the strong emission of the UV could be assigned to the entrance of the electron beam into the nanotube where it can travel adopting a helical path by striking again and again with the inner surface of the nanotube.
Emission E2 can be assigned to the recombination of trapped electrons at Vs and holes trapped at interstitial metal (IS) point defects and E3 is attributed to the recombination between vacancy trap states (VS VM).
Considering the blue shift of the absorption position from the bulk TiO2, the absorption onset of the present samples can be assigned to the direct transition of electrons in the TiO2 nanocrystals.
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