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Both surface oxides and atomic oxygen chemisorbed on metallic surfaces can be active for CO oxidation depending on surface geometric structure.
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Gates and co-workers [10, 11] also managed to produce a Au/MgO catalyst that was active for CO oxidation at 30°C by bringing Au(CH3 2 acac) (acac is acetylacetonate) in contact with partially dehydroxylated MgO and by treatment in flowing helium at 473 K, during which the original mononuclear Au III) species decomposed, gold being reduced and aggregated.
This must be active for 2 years.
Rh supported on CeO2 was active for NOx and CO conversions but could be deactivated easily by high temperature aging.
Y-induced oxygen vacancies are active for O2 activation, whereas oxygen co-ordinatively unsaturated Zr cations (Zr-CUS) located at corners, edges, steps and kinks are responsible for N2O activation.
The catalysts were active for the formation of oxygenates by CO hydrogenation and the vapor phase hydroformylation of ethene.
It is shown that all Co-based catalysts are active for ORR.
Co-zeolite catalysts are active for the NOx selective reduction with CH4.
The Co modified glassy carbon electrodes are active for the electrocatalytic reduction of dioxygen in acidic media.
(8) Sekiguchi and co-workers found that the linker segment of nephronectin was active for binding to α8β1.
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