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The salen- type ligands (HL and HL1) are able to provide the most plausible geometry for 1 2 complexes which appeared to be a square planar (four coordinated) geometry around the M (II) ions.
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Single crystal diffraction study revealed that the complex is a square planar four-coordinated platinum II) complex.
The X-ray absorption fine structure (XAFS) of the Fe-K edge showed that the unit was a square planar Fe N4 moiety.
As shown in Figure 4, Im0 is a square-planar tetracoordinate rhodium(I) complex with C s symmetry.
η -BQ association: The post-insertion complex V is a square-planar PdII complex without any empty acceptor orbitals available for bonding.
Don't be a square.
It should be a square.
MAP is composed of a three amino acid sequence (Asn-Cys-Cys; NCC), and when positioned inline, the metal is coordinated in a square planar organization by two thiolate ligands and two deprotonated amide nitrogens from the peptide backbone.
The complex formed by a discrete PdCl42− anion and one protonated C4H10NO+ cation and the Pd (II) ion is located on an inversion center and is coordinated by four chlorine in a square planar geometry.
On the basis of these studies a square planar geometry has been proposed around the metal ion.
A square planar copper II) complex has been synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction study.
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