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Under reducing-to-moderately oxidizing conditions, a zero-order O2 pressure dependence is found which can be interpreted on the basis of a mechanism involving a reaction between CO adsorbed on Pd and surface oxygen from the support.
The potentiodynamic E/i curves for the silver sulfide monolayer were simulated by computer on the basis of a mechanism of the initial adsorption of HS− on the silver surface in a fast equilibrium step followed by a rate determining electron transfer step to form AgHS as a surface intermediate.
These results also can be explained on the basis of a mechanism change from liquid-gel separation to liquid-liquid separation.
The purposes of these experiments were mainly two-fold: (1) to show the utility of MgZ in sensor development; (2) to demonstrate that NAE sensors can also be engineered on the basis of a mechanism that regulates the accessibility of the substrate through ligand binding.
Both transformations could be rationalized on the basis of a mechanism involving the trifluoromethylation of the activated alkene to give an alkyl radical intermediate 21 as shown in Scheme 16.
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It seems that almost any process of material transformation, mechanical, chemical, or physical, may form the basis of a wear mechanism.
The product patterns are analysed on the basis of a detailed mechanism in the following paper.
The results obtained can be interpreted on the basis of a proposed mechanism in which RhH PPh3)3 is the active species.
This dissertation presents a new type of analysis, called use analysis, forming the basis of a termination mechanism designed to yield a better combination of residual code quality and frequent termination than the current state-of-the-art.
Thus the identification of carbamylation as a PTM in haemoglobin and RuBisCO led to the proposal that carbamylation of neutral N-terminal α-amino groups and the ε-amino group of lysine side chains could form the basis of a widespread mechanism for biological regulation16.
The adsorption/desorption of the reactants on the active sites and the surface reaction is modeled on the basis of a Langmuir Hinshelwood mechanism.
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