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Our studies showed that temperature, solvent, electronic and steric properties of substituents and addition of acidic or basic additives have a strong impact on hydroamination reaction.
In the screening step, the nature and concentration of both acidic and basic additives were found to have a significant effect on retention, selectivity and resolution.
The selectivity of oxygenates, especially C2-oxygenates, was strongly enhanced by a further modification with basic additives such as alkali and alkaline earth cations.
Similar cobalt catalysts were prepared from C02 CO 8 on other oxide supports and some oxides showed a similar effect on the basic additives.
The presence of these sites provides a mechanism whereby the basic additives in CHSs can be adsorbed at the solvent phase/solid phase interface.
The comparison of the different voltammetric behavior in the presence of the different acidic and basic additives allowed constructing an acidity level scale where the different acid base couples of the intermediaries of the NG electroreduction were placed.
Similar(51)
Nevertheless, addition of the basic additive at higher loading in the support resulted detrimental on saturating properties of corresponding noble metal-based catalyst.
The group used PLA plastic, one of the cheapest and most basic additive printing substrates.
Furthermore, the inner P4VP layer also served as a basic additive in the condensation reaction process, while much less homogeneous basic additive was used.
From furfural, 93.0% conversion and 98.5% selectivity toward methylfuroate were achieved under 0.5 MPa O2 with reaction at 100 °C for 12 h without a basic additive.
The GMax is a fairly basic additive printer with a few tricks up its sleeve.
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CEO of Professional Science Editing for Scientists @ prosciediting.com