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To a crystallographer, it is crystal design based on hydrogen bonds and intermolecular interactions.
The chemosensor for ATP based on hydrogen bonds interaction provided a novel strategy for the design of colormetric and ratiometric fluorescent probes for other target anions with high sensitivity and selectivity.
Based on hydrogen bonds that tolerate the thermal curing and the possibility to tailor the self-organized morphologies, it is suggested that the properties of phenolic thermosets might be tailored in a systematic way, upon blending with proper block copolymers.
They proved that the number of interactions to the terminal nitrogen atoms of the azide only depends on steric effects, thus supramolecular systems based on hydrogen bonds to an azide will be independent from the torsions involving terminal atoms of the azide.
The target compounds 4a 4d were designed to form complexes with anions based on hydrogen bonds and electrostatic interactions in acidic aqueous solutions and the interaction constant 1770 mol−1 dm3 of a 1 1 complex was obtained for the interaction of 4c with sulfate anion in 5 × 10−3 M aqueous HCl.
The models based on hydrogen bonds, van der Waals, and hydrophobic interactions gave the best AUC values, while the schema taking into account only hydrogen bonds gave the worst prediction (Table S3).
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In this case, the guest acted as a template for the formation of helicates based on hydrogen bonding and biased the formation of one of the two equilibrium structures.
The molecular recognition is usually based on hydrogen bonding.
Firstly, typical anion ligands based on hydrogen bonding are briefly summarized.
Molecular recognition based on hydrogen bond interaction plays a significant role in supramolecular self-assembly.
The main two strategies that are used for crystal engineering are based on hydrogen bonding and coordination bonding [6].
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