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In addition, there are several reports which have applied the MOF [22, 23, 24, 25], Pd [40, 41] and SWCNT [37, 38] as adsorbent for hydrogen, and one of the famous mechanisms for electrochemical HER in acidic media is based on hydrogen adsorption on the electrode surface in the rate determining step (Volmer reaction) [42].
The electrochemically active surface area of the nanowire arrays was determined by cyclic voltammetry based on hydrogen adsorption.
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This conclusion is again based on hydrogen exchange NMR studies.
Furthermore, there is no theoretical investigation on hydrogen adsorption in Ni-doped TiO2 oxide.
This allowed us to illustrate the concentration of the doping atom on hydrogen adsorption in SWSiCNT.
We explored the effects of pressure on hydrogen adsorption in both materials.
Analogous studies on hydrogen adsorption also suggest interactions with carboxylate O atoms.
The ECSA was calculated from the integrated charge associated with the hydrogen adsorption region which is based on a monolayer hydrogen adsorption on platinum and gives a measure of the HOR.
To describe the kinetics, a Langmuir Hinshelwood model based on adsorption of hydrogen and organic species on different active sites has been applied.
The system is based on an adsorption cryo pump to stimulate the hydrogen flow and on a cold adsorbent for the hydrogen cleaning.
The experimental kinetics was described with a rate equation based on rapid adsorption and desorption steps and slow consecutive hydrogen steps.
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