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The most interesting aspect arising from these studies is that anion transporters based on halogen bonds can be very small, as a consequence of the intrinsic high hydrophobicity of halogen bond-donors.
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Such alternative adsorption models can meet the requirements of different self-assembly systems based on halogen bonding.
Due to its hydrophobic nature, small-sized ion-transport systems can be designed based on halogen bonding.
We expect that materials designed based on halogen bonding could lead to applications in biomimetics, optics/photonics, functional surfaces, and photoswitchable supramolecules.
Sample heating was performed using a specially designed in situ pyrolysis furnace based on halogen lamps with elliptical-shaped reflectors.
The system 1 was a rather good transporter, whereas 2, based on strong halogen bonding, was practically inactive.
Later on, phosphorescent cocrystals based on C I···π halogen bonding between 1,4-diiodotetrafluorobenzene and various conjugated π-electron donor systems have been constructed.
However, currently available crystallographic data on halogen bonds in the PDB is inadequate to accurately define a knowledge-based scoring function.
The formation of two organic interpenetrated networks on halogen bonding driven self-assembly of diiodoperfluorarenes with tetrapyridyl tectons is described.
Published as part of the Crystal Growth & Design virtual special issue on Halogen Bonding in Crystal Engineering: Fundamentals and Applications Halogen atoms are common substituents in a highly diverse range of molecules and subject to noncovalent interactions in both solution and the solid state.
There are two types of interactions with CNT surfaces: those based on covalent bonds and those based on noncovalent bonds.
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