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Such alternative adsorption models can meet the requirements of different self-assembly systems based on halogen bonding.
Due to its hydrophobic nature, small-sized ion-transport systems can be designed based on halogen bonding.
We expect that materials designed based on halogen bonding could lead to applications in biomimetics, optics/photonics, functional surfaces, and photoswitchable supramolecules.
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The most interesting aspect arising from these studies is that anion transporters based on halogen bonds can be very small, as a consequence of the intrinsic high hydrophobicity of halogen bond-donors.
Sample heating was performed using a specially designed in situ pyrolysis furnace based on halogen lamps with elliptical-shaped reflectors.
The system 1 was a rather good transporter, whereas 2, based on strong halogen bonding, was practically inactive.
Later on, phosphorescent cocrystals based on C I···π halogen bonding between 1,4-diiodotetrafluorobenzene and various conjugated π-electron donor systems have been constructed.
The formation of two organic interpenetrated networks on halogen bonding driven self-assembly of diiodoperfluorarenes with tetrapyridyl tectons is described.
Published as part of the Crystal Growth & Design virtual special issue on Halogen Bonding in Crystal Engineering: Fundamentals and Applications Halogen atoms are common substituents in a highly diverse range of molecules and subject to noncovalent interactions in both solution and the solid state.
However, currently available crystallographic data on halogen bonds in the PDB is inadequate to accurately define a knowledge-based scoring function.
The classification is based on the bonding type.
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