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Crystal analyses indicate that the right-handed helical assembly is based on coordination bonds from peripheral to center, associating with the saddle distortion of the molecular planes.
In the case of extended systems based on coordination bonds, the connectivity among the metal centres can be achieved through bridging nucleobases and/or by auxiliary organic linkers such as carboxylate and dicarboxylate anions.
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For the self-coordination frameworks based on coordination game and 3GPP approaches.
Compounds 1 and 2 display the three-dimensional (3D) framework: 1 shows a 3,4-connected topological network with (83)(85·10) topology symbol based on the coordination bonds while in 2, the hydrogen-bonding interactions are observed to connect the 1D linear chain generating a final 3D framework.
The main two strategies that are used for crystal engineering are based on hydrogen bonding and coordination bonding [6].
Intermolecular interactions based on hydrogen bonding (HB) and coordination bonds are by far the most frequently used tools in supramolecular chemistry and especially in crystal engineering.
There are two types of interactions with CNT surfaces: those based on covalent bonds and those based on noncovalent bonds.
The coordination of design systems is based on various coordination modes.
Marschall, M. et al. Random two-dimensional string networks based on divergent coordination assembly.
It is mainly based on the Coordination Theory [24].
However, their mechanisms are based on hybrid coordination function controlled channel access (HCCA) [14].
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