Broad overview of metal complexes designed for the H2S sensor which includes specific examples of copper, zinc, mercury and tin based complexes, has been discussed.
A new effective method for designing unique gigantic polyfunctional macrocarbocycles from cyclic acetylenes and Grignard reagents through the catalytic cyclometalation reaction in the presence of transition metal based complexes has been elaborated.
Several new binuclear and polynuclear dioxomolybdenum VI) Schiff base complexes have been synthesized.
Schiff base complexes have been extensively used in a variety of applications including biological[1], clinical[2], analytical[3], and catalysis[4, 5, 6, 7, 8, 9, 10, 11].
Recently, nickel II) Schiff base complexes have been widely investigated not only for their interesting structures and properties [1, 2], but also for their use as precursor for preparation of nickel oxide nanoparticles [3].
A new family of lanthanide/Schiff base complexes have been synthesized and fully characterized from the novel Schiff base ligand: L1, (E -N′- dipyridin-2-ylmethylene)acE -N′- dipyridin-2-ylmethyleneyridin-2-ylmE -N′- dipyridin-2-ylmethylene
New mono cationic Cu II), Co II), Ni II), VO II) and Zn II) Schiff base complexes have been designed and synthesized from salicylalidene-4-imino-2,3-dimethyl-1-phenyl-3-pyrazolin-5-one and 2-aminothiazole.
To address some of these questions, simple models of the platinum DNA cross-links, such as cis- NH3 2PtG2 (G = detacis- NH3 2PtG2ed Guanine bases) complexes, have been investigated extensively.
Chitosan (CS -based CS -based have been complexesd as a vector for DNA delivery; nonethavess, their transfection efficiency is relatively low.
Only few papers deal with organometallic thiols as capping agents for gold nanoclusters [13] and among metal thiocarboxylates, palladium II -based compalladium II -basedcomplexesnthavezed [14].
A series of blue fluorescent Zn (II) tetradentate Schiff base complexes has been designed and synthesized for applications in organic light-emitting diodes.
