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Loss of the heavier CH3CH2group (m/z= 29) from 2-butanone generates the base peak at m/z= 43.
However, base peak shifting between instrument, i.e. each instrument produced a single base peak but the ion identity was not necessarily the same, did not produce these ripple effects.
Base peak shifting on a single instrument, i.e. one instrument produced multiple base peak ions over the course of the study, generated a ripple effect, where variation across all relative abundances in the effected spectra increased.
Intensities were extracted from recalibrated data as base peak intensities from 10 ppm m/z window around every quantitative m/z target per scan per sample.
The strongest peak in the spectrum is known as the base peak, and its intensity is arbitrarily set at a value of 100.
base peak ion.
Thus, the base peak ion can be regarded as an ion specific for β-hydroxy ceramide.
The high resolution mass Base Peak Chromatogram (BPC) spectra offered accurate ion molecular formulas ([M + H]+).
The base peak at m/z 248 was due to β-type triterpenes.
The base peak of Al2O3 can be assigned to cubic (NaCl structure) with a lattice parameter of 7.95 Å.
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Figure 5 shows the base-peak chromatogram for a 60 min gradient elution.
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