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In the IR spectra of the synthesized complexes 1 3 also these bands are noticed at slightly lower frequency regions evidencing the presence of nitroaromatic moiety in them.
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The attribute surface plasmon absorption bands were noticed at 410 nm and increase of nanoparticles size can also affect the SPR band broadening [20].
In the IR spectrum of TNCB, corresponding to the stretching vibrational mode of C Cl bond, a strong sharp absorption band is noticed at ~718 cm−1, which is absent in the carbon bonded anionic sigma complexes 1 to 3 clearly denotes that there is removal of chlorine atom during the formation of them.
With 50 kGy, the smear appeared to have faded drastically in intensity while a much more prominent high molecular band was noticed at the top of the gel lane, presumably consisting of aggregated or cross-linked proteins (Fig. 5B, lane 7).
Four absorption bands were noticed for the copolymerization in contrast to the three bands for homopolymerization.
On forming FS GNPs, a quenching in the intensity of these two bands is noticed.
However on treatment with copper nanoparticles, additional absorption bands can be noticed at 2922.50, 1408.84, 1339.09, 894.39 and 871.81 cm−1 while other absorption spectrum remains unchanged.
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The main band position with SERS was noticed at 1594 cm−1 (C C stretching vibration).
Additionally, wider peak absorption at the first peak of Q band is noticed in the UV-vis absorption spectrum of VOPcPhO PC71BM composite nanotubes.
A strong decrease of reflectance can be noticed at approximately 380 nm in all sample spectra, this being attributed to the band-to-band transition in ZnO.
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