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The observed increase in the band gap is explained on the basis of quantum size effects.
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However, using PVs only 61% of the gap is explained.
The presence of the Mn3+ and Mn4+ produces colour centres due to unpaired electrons in the d orbital that narrows the band gap which is explained in detail in the XPS discussion below.
A complete band gap is observed (shaded frequency range).
The fundamental band gap is determined to be 2.83 eV.
The band gap is nearly constant, at 3.27 eV.
As the band inversion of this TI accompanies with an indirect band gap, the TI bulk band gap is the indirect band gap, not the SOC gap.
This energy band gap is within optimal band gap range useful for long wavelength absorption.
The optical band gap is the value of optical energy gap between the valance band and the conduction band.
The highest band gap is related to S-A-3.
The band gap is also calculated from photoluminescence.
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