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Ligand exchange with retention of the cluster core requires a simultaneous balancing of charge and coordination sites.[ 5, 6] When the leaving and entering ligands are different, the risk of cluster degradation or rearrangement is high, even if both have the same charge and coordination characteristics.
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The structures reported in this article impressively demonstrate the subtle balancing of charges and coordination behavior of both the metals and the ligands to reach a stable cluster.
Balancing of charges and coordination numbers is achieved by two bridging O iPr ligands (connecting the two edge-sharing octahedra), eight bridging carboxylate ligands and six terminal O iPr ligands.
The balance of charge is measured by an in situ charge monitor, which simulates the charge on a CMOS gate.
Moreover, the incorporation of F atoms into complex 3 (3b, 3b) can be efficient approach of tuning the electron injection ability, balance of charge transfer process, and emitting color.
TAZBTF exhibited maximum electroluminescence efficiency as high as 2.60 cd/A, demonstrating that a good balance of charge carriers is injected into our devices.
The results indicate that the incorporation of Au NPs can significantly improve the hole current, that is to say that the doping of Au NPs is in favor of the hole injection, then leads to the balance of charge injection.
When the Zn +2 ions are replaced with Fe +3 ions, the oxygen ions would be drawn to the Fe +3 ions to keep the balance of charge [39, 40].
Although we are considering only a balance of charge in the present case, the analysis can be extended to other conservation equations (e.g., for mass, momentum, and energy) to support a multiphysics design with a more general discussion.
A delicate balance of charge, polarity, and hydrophobic character determines the secondary structures of protein.
In order to keep the balance of charges, the amount of Mn2+ and Mn7+ ions differs with the doping of Sr2+ while the total molar amount of them was 0.0125 mol.
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