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The second is to add the backward reaction term to the power law models.
This is a reversible reaction with almost equal forward and backward reaction rate.
The forward and backward reaction rate of each intermediate reaction is calculated applying transition state theory.
Lithiation of Fe3O4 and its backward reaction is chosen as a case study process.
The deviation from linearity in the alkaline range is due to the increasing backward reaction in step (1).
The improved H2 yield was due to the prevention of the water-splitting backward reaction in the twin reactor.
Under CO2-rich concentration, endothermic reaction (backward reaction of R3) also increases, resulting in a decrease in gas temperature.
The quenching of the MnO is very important to stop backward reaction, i.e., formation of Mn3O4 again.
Analytical solutions are presented for the above cases under conditions of negligible backward reaction rate and interaction parameter g.
Apparent activation energy of 31.2 kJ/mol for the forward reaction and 27.7 kJ/mol for the backward reaction was obtained.
With help of HC, photocatalytic generated oxygen was captured by HC and transferred away from photocatalyst surface, then the backward reaction of hydrogen-oxygen recombination was successfully restrained.
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CEO of Professional Science Editing for Scientists @ prosciediting.com