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In particular, we will focus on the role of the bridge in forward and backward electron transfer processes, and on the possibility of obtaining efficient photoinduced charge separation even when the driving force for the electron transfer process approaches zero.
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The molecular model of the reaction centre was calculated from the data of crystal structure downloaded from the Brookhaven Protein Data Bank (www.rcsb.org, code name: 1pst) Fig. 4 The lifetimes of the forward (blue solid arrows) and the backward recombination (red dashed arrows) electron transfer steps between the cofactors of the RC.
The redox potentials shown in Figure 13 and Table 1 are derived from fitting the forward and backward rate constants to empirical electron transfer rate equations to estimate free energy differences and reorganization energies.
Protein-mediated electronic interactions facilitate biological electron transfer (ET) reactions.
Wong, C. L. & Kochi, J. K. Electron transfer with organometals.
Lovley, D. R. Syntrophy goes electric: direct interspecies electron transfer.
Li, B. et al. Ultrafast interfacial proton-coupled electron transfer.
Oxidation-reduction reactions occur with electron transfer between reagents.
They constitute the electron transfer system, or respiratory chain.
Kato, S. Biotechnological Aspects of Microbial Extracellular Electron Transfer.
Reguera, G. et al. Extracellular electron transfer via microbial nanowires.
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