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The short-circuiting back electron transfer process is significantly slower in the zeolite.
The results indicate that the design strategy is highly efficient in reducing the rate of back electron transfer, which results in long lived charge-separated excited states.
The charge-shifted state decays via back electron transfer (BET) to the ground state rather than to the triplet excited state.
This work demonstrates that the smaller distance of separation between the anchoring units increases the insulating capacity of the molecular layer which retards the back electron transfer.
Detailed balance is broken and a net flux of rings occurs as they shift their allegiance to the unreduced station 2. After 10 microseconds, however, as back electron transfer finally takes place, station 1 regains its stickiness.
The experimental data is fitted and rate constants for electron transfer from the nanoparticle to the substrate, hole capture, recombination and back electron transfer are determined.
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The development of efficient photocatalysts for high chemical conversion efficiency solely relies on the means to suppress back-electron transfer or electron hole pair recombination process.
The specific molecular design of porphyrin sensitizers significantly retards the rate of interfacial back-electron transfer from the conduction band of the nanocrystalline titanium dioxide photoanode to the oxidized cobalt mediator, leading to the attainment of extraordinarily high photovoltage of about 1 volt [141].
To find further evidence of the correlation between the effect of insulating layer and the suppression of back electron process and electron transfer rate, electrochemical impedance analyses (EIS) and the intensity modulated photocurrent/voltage spectroscopy (IMPS/IMVS) studies are performed under standard conditions.
In the presence of a reducing gas (e.g., HCHO), a chemical reaction between gas molecules and oxygen species leads to electron transfer back into ZnO, thereby increasing its conductivity [29].
The ACP radical then undergoes electrophilic attack on the π orbitals of the ε carbon of the imidazole ring on EF, forming an imidazole-based radical that may be quenched via electron transfer back to the [4Fe 4S] cluster upon deprotonation.
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