Sentence examples for available coordination from inspiring English sources

Apparently this is not possible for steric reasons, and two OMc ligands coordinate only in an η manner; to occupy all the available coordination sites two neutral McOH ligands are additionally coordinated to the same Ti atom (Ti2).

The most extensively studied ones thus far are complexes composed of tetradentate N4 ligands that have cis-oriented available coordination sites, analogous to those observed for the Rieske dioxygenase enzymes.

In this work the electrochemical behavior, of three Fe(II) polypyridinc complexes [Fe(bipy 3]2+, [Fe phen 3]2+, and [Fe terpy)2]2+ in acetonitrile solution was explored, to understand the mechanism of the molecular catalysis of carbon dioxide reduction, for metal complexes with no available coordination sites and inert to substitution.

The mononuclear oxalato-containing chromium III) complexes of general formula [Cr AA)(C2O4 2]− (AA = α-diimine type ligand) are able to produce a large variety of heterometallic complexes by acting as ligands towards either fully solvated metal ions or preformed cationic complexes with available coordination sites.

This may be easily explained by that the initial CoII(Himid) moiety has even five available coordination sites that can be occupied by two carboxyl groups and one amino group.

As compared to other available coordination solvents such as OA and OM, the free-energy barrier for the cubic → hexagonal phase transition was significantly reduced in TOPO.

Therefore, each phosphorus atom is available for coordination to copper ions allowing an 1,2,3,4,5-coordination mode as in other pentaphosphaferrocene-based supramolecules.[ 5] Each of the (CpBnFeP5 2(CuL)(Cu2I 4 building blocks is connected to four {CuI4} tetrahedra and four other similar building blocks, which are rotated by 90° in two perpendicular directions.

Simple β-diketonates have two oxygen atoms available for coordination and tend to form 3 1 complexes with lanthanides, with the remaining vacant sites in the lanthanide coordination sphere being occupied by water molecules.

Today, numerous methods of communication are available for coordination between the Weather Service and communities that need to act on the forecasts.

When the other element is lower in electronegativity than nitrogen, the polarity gives partial negative charge to the nitrogen atom, making its lone-pair electrons available for coordination.

Heeding this call requires first and foremost that nations support the development of a robust commitments mechanism that can efficiently take stock of national efforts and at the same time increase the resources available for coordination.