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The Au-M (M=Pd, Pt) nanostructures are of typically core-shell type structure where Au forms the core and the shell is made of either Pd or Pt.
We hypothesize that when the complementary single-stranded DNA attached to the Au forms the more stable double strand, the Au reorganizes on the microgel surface, yielding the observed unique Janus particle structures.
The dependence of the limiting current, ilim, on the rotation rate of the RDE was found to display classical Levich behavior up to potentials well within the range in which Au forms a surface oxide in the neat (sulfite-free) supporting electrolyte.
Vahidi et al. [35] reported that Au forms a robust electronic bond with free thiols.
On the other hand, Au forms two deep trap levels in Si.
A computational study found that Au forms a tunnel barrier contact while Titanium (Ti) forms a more electron injection-efficient low resistance Ohmic contact on a monolayer thick MoS2[93].
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In addition to those of the alkali metals and the alkaline-earth metals mentioned above, lanthanum (La) forms two different acetylides, and copper (Cu), silver (Ag), and gold (Au) form explosive acetylides.
Vahidi et al. [35] reported that Au form a robust electronic bond with free thiols.
Furthermore, Si and Au form a eutectic at a concentration of about 31 a/o Si-Au and temperature of 370°C.
Therefore, as Au formed a thin wall layer (< 4 nm) on the Ag core wire, the surface plasmon absorption band showed only one peak, which is in agreement with the experimental result [6].
The complete consumption of Ag along with the precipitation of Au atoms formed Au ring-like nanostructures.
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