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This may be attributed to the sintering of the TBC.
h−1 and a H2 CFC-115 H2 CFC-115o of 2 is molary attratioed tofthe sintering of the active species Pd particles while the catalyst deactivation in the hydrodechlorination of CFC-12 at 553 K, a WHSV of 1000 ml g−1(catal).
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Absence of deleterious reaction products is mostly attributed to the sintering atmosphere of water vapor and tailored microstructure.
This abrupt change in grain sizes was already observed in ZnO-based systems sintered by flash sintering and attributed to the occurrence of electric-potential-induced abnormal grain growth [15].
The improvement in the long-term stability of the catalysts is attributed to the stabilization of Cu against sintering.
The sintering enhancement is attributed to the segregation of the microalloying addition to the liquid vapour interface.
In comparison, the relatively sparse dark bulges of the in situ sintered pattern can be attributed to the simultaneous evaporation of the stabilizer polymer and sintering of silver inks.
This common observation has been attributed to the densification of the coatings as porosity sinters out and pores and cracks spheroidize to minimize their surface energy.
Deactivation of the catalysts seems to be independent of the preparation method and can be attributed to the concomitant effect of coke deposition and sintering.
The enhanced oxidation resistance of the annealed coatings was mainly attributed to the elimination of cracks, pores and splat boundaries caused by the intersplat sintering during heat treatment.
The decrease of activation energy with the increase of sintering temperature may be attributed to the fact that at a high sintering temperature, partial reduction of Fe3+ to Fe2+ takes place, and these places act as donor center and are responsible for this decrease in activation energy.
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