Sentence examples for attacks the ferryl from inspiring English sources

Finally, hypochlorite attacks the ferryl oxygen and chloride and O2 are released.

Despite the importance of the chemical steps leading up to formation of the ferryl, these steps remain largely uncharacterized.

In contrast, the observed kcat/ KM O2) is inconsistent with the O EIE calculated for X = ferryl (O EIE = 1.0287), indicating that the ferryl intermediate is formed after the rate-limiting step on kcat/ KM O2) in FIH.

Finally, hypochlorite rebinds to the ferryl oxygen of Compound I, and chloride and dioxygen are released (reaction 3).

The spectrum of the ferryl species has a Soret peak of 418 nm and α and β peaks of 562 and 542 nm respectively, consistent with the spectrum of ferryl Mb.

Consequently, O2 activation is too rapid to allow for the identification of any intermediates prior to the ferryl.

The ferryl form of wildtype cytoglobin is unstable, but is able to readily oxidize substrates such as guaiacol.

In the final reaction, hypochlorite recombines with the ferryl oxygen of compound I thereby releasing O2 and chloride.

Alkaline conditions stabilize the ferryl species, making myoglobin considerably less reactive towards lipids and lipid hydroperoxides [ 31].

Nevertheless, uncoupling in the variants depended on solvent isotopic composition (Table 3), suggesting that the ferryl intermediate could form even when CTAD was improperly positioned.

Even though Asn103 is unable to directly form a hydrogen bond with the ferryl heme moiety in Q103N MauG, the high-valence species is still relatively stable.