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The possible reason can be related to quantum confinement: the surface atoms can move more easily than the bulk where the atoms are fully locked in the lattice [32].
This interaction could occur in any MCM protein because the constituent atoms are fully conserved.
The majority of clathrates adopt the composition nearly corresponding the case when electrons donated by the electropositive guest atoms are fully used up by the more electronegative framework acceptor atoms for the fulfillment of their covalent bond requirements.
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In order to optimize atomic geometries, the position of all carbon atoms was fully relaxed.
Once the neutral atoms were fully grown in the solvent, the second simulations then computed the free energy associated with the electrostatics with a soft-core scaling parameter of 0.0.
Betaines are amino acid derivatives in which the nitrogen atom is fully methylated such as that of quaternary ammonium compounds.
This simple analysis clearly shows that the long surface Fe OH2 distance can be rationalized by the fact that the surface Fe3+ atoms are already fully charge balanced (i.e. valence saturated) with only 5 neighbors.
In the Sun's outer layer, from its surface to approximately 200,000 km below (70% of the solar radius from the center), the temperature is lower than in the radiative zone and heavier atoms are not fully ionized.
This behaviour may be explained in terms of the poor hydrogenating capacity of Ni compared to Pt [44], making it more difficult for the Ni atoms to be fully reduced, so that not enough Ni metallic sites were available to sustain the reaction, since the hydroisomerisation reaction includes a dehydrogenation step [40, 42].
Saturated fat, a fatty acid in which the hydrocarbon molecules have a hydrogen atom on every carbon and thus are fully hydrogenated.
An addition reaction may be visualized as a process by which the double or triple bonds are fully or partially broken in order to accommodate additional atoms or groups of atoms in the molecule.
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