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Large systems operate at large cycle times, obtaining up to 98% of H2 recovery in the order of hours, whereas small systems can recover up to 60% of H2 in short cycles of a few seconds.
The appropriate value of Ω depends on the cycle time and to a lesser extent on the degree of isotherm non-linearity and the nature of the diffusion mechanism, varying from about 40 at low cycle times to 15 or even lower at large cycle times.
On the contrary, rGO had good performance at large cycle stability.
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The value of Ω recommended by Glueckauf for modelling of a fixed bed (Ω = 15) is approached only at rather large cycle times and is clearly inappropriate for a PSA system under most practical conditions.
At very large cycle times, subjects could see the single line jumping from position to position.
However, this technique still faces challenges in attaining high selectivity, especially at large MLD cycle numbers.
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