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Samples were synthesized at injection temperature 447 ± 0.5 K, (frac{[Co]}{[OA]} = 12.9,) injection time = 5 s, reaction holding time = 1800 s.
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An interesting behavior was though observed for supercritical injection temperatures: when the impinged surface is still at subcritical temperatures, the peak of the water's specific heat at the pseudo-critical temperature dominates the heat transfer even at injection temperatures far beyond the pseudo-critical temperature.
The FID detector temperature was 320°C and 1 μL was injected at an injection temperature of 250°C and a split level of 1 2.
Aliquots of 1 μl were injected in the splitless mode at 270 °C injection temperature with helium as carrier gas at a flow rate of 0.9 ml/min in constant flow mode.
Aliquots of 1 μl were injected in the splitless mode at 270 °C injection temperature with helium as a carrier gas at a flow rate of 0.9 ml/min in constant flow mode.
The gas chromatograph was operated at an injection temperature of 200°C with 1 μL of sample injected with the AOC-20i Shimadzu auto injector.
Injection was performed in a splitless mode at an injection temperature of 280°C.
The samples were analysed in splitless mode at an injection temperature of 250 °C and detector temperature 280 °C.
In comparison with solid PP, the 4.23% weight reduction, 16.52% increase of flexural strength and 20% increase of flexural modulus were achieved by the all-PP composite foams produced at the injection temperature of 220 °C and injection speed of 40 mm/s.
Splitless injection of 1 μl sample aliquots was performed with an Agilent 7683B auto sampler at an injection temperature of 270°C (2 respectively 5 pre/post-wash cycles were used with hexane).
We suggest that introducing the bulky tert-butyl group creates less nuclei at the same injection temperature and allows further growth using unreacted P precursors in the solution.
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