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The phrase "at critical junctures" is correct and usable in written English.
It can be used to refer to important moments or turning points in a process or situation where significant decisions or actions are required.
Example: "The team made several key decisions at critical junctures that ultimately determined the project's success."
Alternatives: "at crucial moments" or "during pivotal times".
Exact(60)
At critical junctures, they were rescued by sympathetic white people.
That's dangerous because they stand at critical junctures.
At critical junctures of her life, Hillary makes the same mistake.
At critical junctures of Mr. Obama's career, the subject of nuclear disarmament has kept reappearing.
Its weakness lies in its failure to explain why, at critical junctures, we disown that knowledge.
I always turned to him at critical junctures in my career.
Civilians — and the information they might choose to provide — can turn the tide at critical junctures.
If the superdelegates were created to solve deadlocks and other party problems, then you can't nullify them at critical junctures.
At critical junctures throughout the crisis, Mrs. Merkel has resisted appeals to appease the financial markets by lowering borrowing costs.
Still, in today's game, every defense has to count on its linebackers to cover at critical junctures.
Previous attempts to capture him had failed in part because of leaks and indecision at critical junctures.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com