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However, a more complex model was needed to describe PFOA defluorination, so a model was developed that assumed formation of one partially defluorinated intermediate and this model was used to describe the relationship between free fluoride concentration and absorbed dose.
Similarly, Hizal and Apak [28] assumed formation of monodentate Cu complexes on two variable charge sites, presumed to correspond to aluminol and silanol sites.
The assumed formation of semiquinone radical anions is based on their relatively low p Ka value (ca. 5).
We assumed formation of a closed vesicle (i.e., maturation of a PG) to take place in a first-order process with rate constant k ves = 0.05 sec−1 once a threshold level of LC3 has been incorporated into a growing PG.
Nevertheless it is likely that there are two carbonate groups per QNC molecule based on the 1.43 1 ratio found in the electrochemical release case, and also based on the assumed formation of a dienolate structure[ 25] in the QNC molecules.
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The model assumes formation of condensed products and reaction rate controlled by the transport of oxidizer to the particle surface.
Such behavior assumes formation of ZnS nanoparticles, which is favorable at elevated temperatures, migration of Zn ions, and formation of clusters (nanoparticles) of ZnS.
The Freundlich model is another commonly used isotherm model, and if applicable, would assume formation of multilayer of adsorbates on adsorbent's surface, and the D R isotherm also assumes heterogeneous surface of the adsorbent and is temperature dependent.
Since the molecular mechanism of glutamate dehydrogenase assumes formation of the 'iminoglutarate'-like intermediate, several inhibitors of this enzyme were designed as structural analogs of this compound, including 2-methyleneglutarate, isophthalate, and 2,4-pyridinedicarboxylate (Fig. 10a c) (Noor and Punekar 2005).
Scant video remains today of the performance, but Suitor said the marching bands assumed formations resembling a pair of players and that the giant footballs were positioned at each 45-yard line.
It was assumed the formation of the NO3 intermediate is mainly responsible of the corrosion of the graphite in this melt.
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