Sentence examples similar to assignment of configuration from inspiring English sources

Although the initial assignments of configuration for the glyceraldehydes were made on purely arbitrary grounds, studies that were carried out nearly half a century later established them as correct in an absolute spatial sense.

Re-examined of the ROESY spectrum suggested that the mis-assignment of configuration of the epoxy ring as supported by the obvious ROESY correlations between H-8/H-2, and H-2/H-13 (Fig. 5), suggestive of α configuration instead of β configuration of the epoxy ring.

(32) The revised 1989 nomenclature system recommended by the International Union of Pure and Applied Chemistry IUPACC) and the International Union of Biochemistry (IUB) for the naming of sterols and related isoprenoids permits unambiguous assignments of configuration and introduces a convenient and logical uniformity to the nomenclature of all tetracyclic triterpenoids.

The assignment of 8S configuration could be explained in view of its proposed biosynthetic pathway [9].

Each row is a specific test denoted by the ID and the unique assignment of the configuration parameters.

The assignment of absolute configuration was accomplished by NMR, which is supported by corresponding X-ray structure and optical rotation data.

A general protocol for the design of successful chiral derivatizing agents (CDAs) for the NMR assignment of absolute configuration is described.

The link between macroscopic microscopic phenomena and molecular chirality proves that crystals are necessary for the direct assignment of absolute configuration of chiral molecules [16].

This method has been shown to be a useful technique for the assignment of the configuration of the glycosidic linkage for a wide variety of carbohydrates.

Four single-crystal X-ray structure analyses allowed the assignment of the configuration of the phosphorus atom in the diastereomeric phosphites, α-hydroxyphosphonates and phosphates.

Thus, the ECD and UV spectra of 1 were predicted by quantum-chemical calculation using TDDFT not only to verify the assignment of absolute configuration but also to investigate the ECD behavior of the bis(thiosemicarbazone) group.