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The location of the functional group and the assembly of compound 1 were done by HMBC data.
The π-forces are more important than the hydrogen bonding forces in such compounds is evident from the supramolecular assembly of compound 3.
In the self-assembly of compounds 1 3, the introduction of anions with different sizes and geometrical configurations lead to the flexible C C chain of fluconazole to be rotated for suitable position and angle to hold them.
The solvents effects on the self-assemblies of compound 3 were also witnessed by SEM studies.
De novo design requires the assembly of candidate compounds, which are then used to search for novel structures [41].
An analysis of packing reveals that the molecular assembly of these compounds is driven by different infinite and finite chains of hydrogen bonds.
In the previous work, we reported the design and synthesis of functional luminol derivatives with different substituted groups and investigated the interfacial assembly of these compounds with different methods [28, 29].
Pyridine and substituted pyridines are the important intermediates for the synthesis of pharmaceuticals, herbicides, metal corrosion inhibitors, rubber vulcanization accelerators, and conventional ligands for the chemical assembly of coordination compounds [1, 2, 3, 4].
The unsuccessful synthesis of 1 under similar synthesis condition using HLn as reactant suggests the in situ reaction is crucial for the assembly of the compound.
The self-assembly behavior of compound 2 in CH2Cl2 resulted in a decrease of the absorption intensity in the range of 2 × 10−7 ~ 5 × 10−7 M (Bayrak et al. 2011; Öztürk et al. 2012).
The most engineering application for the molecular self-assembly of sulfydryl compounds on solid surfaces is froth flotation.
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