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The phrase 'assemble to' is correct and usable in written English.
This phrase is usually used to indicate that a group of people have gathered to do something, typically some kind of physical task. For example: "The volunteers assembled to help build the playground."
Exact(46)
Artists from Los Angeles began to assemble to the small town of Laguna Beach around 1903.
From there, they invited Assemble to help improve the houses and neighbourhood.
For instance, last year he sent lawmakers subpoenas forcing them to assemble to discuss the budget.
Others were arrested for merely suggesting online that people assemble to protest.
Scene 4 On deck, at four o'clock the same morning, the crew assemble to witness the hanging.
The occasion is Batman's wake, and his enemies and allies assemble to recount their versions of his passing.
Similar(12)
An assemble-to-order (or ATO) system includes several components and several products.
These tryptophan containing peptides can self-assemble to spherical particle.
The surfactants can self-assemble to form aggregates with different microstructures.
POSS-PVim hybrid molecules also self-assemble to form micelles in DMF.
In selective solvents, the BCPs self-assemble to form ordered micellar-like structures.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com