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Discover LudwigThe phrase "as he joined" is correct and usable in written English.
It can be used to indicate the timing of an action occurring simultaneously with someone joining a group or activity.
Example: "As he joined the meeting, everyone turned to greet him warmly."
Alternatives: "when he joined" or "upon his joining".
Exact(60)
He made no comments as he joined his family.
Tate Liverpool opened just as he joined in 1988.
Tsonga's voice trailed off as he joined the others in looking at the crouching photographer.
As soon as he joined a practice in Syosset, he became a fixture in regional theater.
Pickles exacted his revenge on Osborne as he joined the mockery of the chancellor's burger picture.
One member placed a hand on Lewis's back as he joined the chorus.
Adrian Belew has left Nine Inch Nails almost as quickly as he joined them.
Mr. Burckhardt avoided the limelight even as he joined one of modernism's most important circles.
But on Sunday night he put such bleak thoughts to one side as he joined in the celebrations.
"It's the end of the dictator Maliki," said Hatem Tome, 25, as he joined in the dancing in Tahrir Square.
Connections like these made Mr. Crawford skeptical of the back-to-the-land movement, even as he joined it.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com