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The phrase "as chief of" is correct and usable in written English.
It can be used to indicate a person's role or position within an organization or group.
Example: "As chief of the department, she is responsible for overseeing all operations and ensuring that the team meets its goals."
Alternatives: "in the role of chief" or "serving as chief".
Exact(60)
As chief of staff for George Q.
"On my tab, as chief of state".
How long will John Kelly last as chief of staff?
Gen. Meliton Goyena as chief of personnel, Col. Antonio Samonte as chief of intelligence, Col. Alexander Aguirre as chief of operations and Brig.
Ayers serves as chief of staff to Vice President Pence.
Gen. Ramon J. Farolan as chief of the air force.
Yezhov had replaced Yagoda as chief of the NKVD.
Days later, Mr. Priebus was out as chief of staff.
He was succeeded by Ms. Rousseff as chief of staff.
Gen. Rodolfo Caneso as chief of the army, replacing Maj.
He served as chief of staff to then-Sen.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com