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Potassium chloride (KCl) was used as a supporting electrolyte.
NaOH was used as a supporting electrolyte obtained from Raidel De Haen.
0.25 M sodium acetate buffer (Panreac) at pH 4.75 was used as a supporting electrolyte.
0.1 M NaOH (purity > 98%, Lachema, Czech Republic) solution was used as a supporting electrolyte.
The cell contains an excess of sulfuric acid as a supporting electrolyte.
These films were synthesised by anodically polymerising pyrrole in the presence of Acid Red 1 as a supporting electrolyte.
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To obtain a supporting electrolyte curve (as dependence of the changes of pH versus the volume of the added base), 50 cm3 of sodium chloride solution (0.01 mol/dm3) was placed in the thermostated vessel and titrated with NaOH solution (0.1 mol/dm3) [31].
NaCl of concentration 0.01 mole/dm was used as a supported electrolyte.
Therefore, a highly hydrophobic tetraoctylammonium tetrakis pentafluorophenyl borate (TOATB) salt was synthesized and incorporated into the PVC-NPOE gel phase as an organic supporting electrolyte to provide a larger potential window at the negative end.
The electroanalytical experiments were carried out in an electrochemical workstation with a co-solvent (MeOH/H2O = 9.83/1, volume ratio) containing 0.08 M potassium bromide as the supporting electrolyte in a divided glass cell, with a lead plate as the working electrode, a titanium-ruthenium mesh as the counter electrode, and Ag|AgCl|KCl as the reference electrode.
The optimum conditions for the method include an acetic acid acetate buffer mixture (pH 3.4) as supporting electrolyte, an electrolysis potential of −1.1 V and a flow rate of 3 ml min−1.
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