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X = halogen; M = electropositive metal; R1, R2 = aryl, alkyl, vinyl or alkynyl; 1a: 1-haloolefin; 1b: 1,1-dihaloolefin; 2: carbenoid intermediate; 3: carbene intermediate; 4: alkyne.
The hydride transfer initiated cyclization ("HT-cyclization") of aryl alkyl ethers, which leads to direct coupling of sp(3) C-H bonds and activated alkenes, is reported.
By using I at 0.01 0.1 mol%, various kinds of sulfides including aryl, alkyl, and vinyl ones could be converted into the corresponding sulfoxides in excellent yields with one equivalent of H2O2 with respect to sulfides.
The treatment of an aromatic hydrocarbon with an acyl halide or anhydride in the presence of a catalyst composed of a Lewis acid (i.e., a compound capable of accepting an electron pair), most often aluminum chloride (AlCl3), gives an aryl alkyl or diaryl ketone (ArH → ArCOR or ArCOAr′), where Ar represents an aromatic ring.
These molecules were designed to ensure that a diversity of electronic features were represented in the compounds evaluated, including various aryl, alkyl, and amino groups, with both electron donating and electron withdrawing properties.
Paulson and co-workers have reported a gas chromatography-mass spectrometry (GC-MS -based characterization method that converts the sulfate monoester into the correspondinGC-MS -based sulfate diesters, which are stable under temperature proGC-MS -basedonditions [17].
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Design, microwave-assisted synthesis of novel 4-aryl (alkyl)amino-3-nitroquinoline (1a 1l) and 2,4-diaryl (dialkyl)amino-3-nitroquinolines (2a 2k and 3a) via regioselective and complete nucleophilic substitution of 2,4-dichloro-3-nitroquinoline, respectively in water are presented.
Of the surfactants studied, only polyoxy ethylene aryl-alkyl ethers were useful stabilisers, whereas alkyl ester analogues were not.
Hydrophobically modified amphiphilic polyelectrolyte films derived from poly (maleic anhydride-alt-styrene) containing hydrophobic aryl-alkyl type side chains such as phenyl-ethyl, phenyl-butyl, naphthyl-ethyl and naphthyl-butyl were studied by Kelvin probe force microscopy.
CYP 2D6 hydroxylates aromatic rings or an accompanying short side-chain of basic aryl-alkyl amines containing a protonated nitrogen.
Out of a heterogeneous dataset of cPLA2α inhibitors, examples shown in Figure 1, this molecular modeling study focused on three chemical classes that are composed of an aryl-alkyl-/alkyl- oxy) side charyl-alkyl-/alkyl- oxyl moiety, aryl-alkyl-/alkyl- oxywo to three aryl-alkyl-/alkyl- oxy
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