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Compared to lignin, slow dephasing is observed for the aromatic carbons in wood charcoal, and even slower for inorganic carbonate.
Top Hydroxylation of aromatic carbons.
The aromatic carbons appeared between δ 110 153 ppm.
Bottom Hydroxylation of aromatic carbons coupled with halogen migration.
Oxidation of aromatic carbons as well as heteroatoms contained in aromatic rings will be considered.
Other aliphatic and aromatic carbons appeared at their expected chemical shifts.
Oxygen can readily attack the aromatic carbons of furan to ring-open the structure.
Electrophilic attack on aromatic carbons is a useful method for functionalizing aromatic compounds [1 3].
Resonances of aromatic carbons were found in the comparable region around 113.86 135.72 δ ppm.
On the other hand, autoxidation of the aromatic carbons of the 5-membered ring in benzofuran leads to addition products.
It has been shown that oxygen can directly interact with multinuclear aromatics (carbocyclic rings) to oxidize the aromatic carbons.
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