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The two supported Ni catalysts (Ni/ZrO2-CP and Ni/Al2O3-C) exhibit fairly stable catalysis under low GHSVCH4 but they are easily deactivated under high GHSVCH4 and become completely inactive when they are reacted for ca.100 h at GHSVCH4 = 48,000 ml/(h gcat).
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Pt (111) peak emerged after being reacted for 1 h.
The mixture was reacted for 24 h at the room temperature under continuous stirring.
The HA and A-MNCs were reacted for 2 h at room temperature.
The best result was yielded when the reactants were reacted for 60 min.
Briefly, N-BOC-Serinol, HDI, and urea were reacted for 7 days at 90 °C.
The mixture was reacted for 24 h at 30 °C with gentle stirring.
The mixture was reacted for 2 h at 200°C and then further heated at 300°C for 1 h.
Then, 15 mL of degassed chloroform containing Au or Au-Ni NPs was added (1 mg/mL), and the solution was reacted for 6 h in a shaker.
Figure 3 29 Si MAS NMR (a) and 27 Al MAS NMR (b) of tobermorite that had been reacted for t = 24 h (solution:solid 5 1).
Then, the degradation was done by rapidly adding H2O2 (with different concentrations) and was carried out with ultrasonic irradiation for 3 min. The solution was reacted for 20 min. Lastly, the Fe3O4 microspheres were collected using a magnet.
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