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The phrase "are most effective when" is correct and usable in written English.
It can be used to describe conditions or situations under which something achieves its highest level of effectiveness.
Example: "These strategies are most effective when implemented consistently over time."
Alternatives: "are most successful when" or "work best when".
Exact(59)
Lies are most effective when the liar believes them.
Vaccinations for infectious diseases are most effective when coverage is near universal.
Heroes are most effective when the need for them is greatest, as God Loves Caviar shows.
Abstract Treatments for diseases are most effective when the disease is noticed at the earliest stage.
Strategic priorities are most effective when they meet a specific set of criteria.
Note: Topical treatments are most effective when applied in the fall, from November to early December.
Massage and stretching are most effective when they are gentle and gradual.
Machine learning methods are most effective when they optimize an appropriate performance measure.
Sense memories are most effective when you're allowed to discover them yourself.
The matching hypothesis states that recovery strategies are most effective when they match particular sport demands.
The Ohio case provides a much clearer lesson: prison libraries are most effective when they manage to confine the prisoners.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com