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Hapticity is how a group of contiguous atoms of a ligand are coordinated to a central atom; it is indicated by the Greek character eta, η.
The carboxylate groups of these residues are coordinated to a magnesium ion that is essential for catalyzing excision of the misincorporated base.
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Ferrocene (Figure 1) is a peculiar organometallic compound, with a sandwich structure where two cyclopentadienate (Cp) groups are coordinated to an iron atom, formally Fe(II).
The carbonyl group of the peptide bond is coordinated to a conserved asparagine (Asn156) on H5, forming a ligand-coordinated bridge between the two six-helix bundles.
One [Cu phen 2]2+ unit is coordinated to a terminal oxygen and the other [Cu phen 2]2+ unit is coordinated to a bridging oxygen of the polyoxoanion.
Each of the Pb II) ion is coordinated to a PHEN and 5-BTPC in a bidentate chelating mode.
Changes in electrochemical reactivity for lawsone anions (lawsone, 2-hydroxy-1,4-naphthoquinone, HLw) being coordinated to a series of metallic ions in dimethylsulfoxide solution were evaluated.
Developing Re(V -based therapeutic agents, where the ReO3+ core is coordinated to a multidentate ligand, is of interest in the radiopharmaceutical sciences because of the desirable nuclear properties of 186Re/188Re.
This is in keeping with our previous observations that the cisoid conformation is preferred when the anion is coordinated to a metal ion, while the transoid is preferred for noncoordinating cations.
In the case of the hexa-monodentate thiazolyl ligand 4, only every second ring is coordinated to a silver cation.
Along the Jahn Teller axis, Mn1 is coordinated to a μ3-hydroxide (Mn1 O10 2.195(4) Å) and a terminally bound dmf (Mn1 O12 2.243(4) Å) in the TBC[4] cavity.
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