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The phrase "approach when comparing" is correct and usable in written English.
It can be used when discussing the method or perspective taken during a comparison of two or more items, concepts, or data sets.
Example: "When analyzing the two studies, it is important to adopt a critical approach when comparing their methodologies and results."
Alternatives: "method when comparing" or "perspective during comparison".
Exact(6)
Shubin takes a similar approach when comparing the eyes of a limpet, nautilus, scallop, and human, pointing out similarities in tissue and genes with attention to the role of opsins in the seeing process.
We used the same approach when comparing the effect of genotype on the clinical characteristics of BD patients.
In fact, this observation argues in favour of a non-stage-matched approach when comparing IBC to non-IBC.
The analysis also demonstrates the value of a systematic approach when comparing a therapy cohort to corresponding therapy cohorts.
Normalization is a widely used approach when comparing the levels of lipids, proteins or mRNA in two or more groups of samples.
Studies investigating VO2 kinetics when performing to exhaustion have been conducted mainly in cycle ergometry and treadmill exercise, presenting a pretty simplistic approach when comparing different exercise intensities.
Similar(54)
Control tests show the usefulness of the proposed approach when compared with other tuning techniques.
A case study illustrates the benefits of the new approach when compared to a conventional design.
It has gained popularity around the world since its 2010 launch but has drawn controversy over its aggressive approach when compared to traditional taxi services.
Experimental results are provided that highlight the effectiveness of the proposed approach when compared with some existing DAPC techniques.
Numerical examples from the literature are used to illustrate the potentialities of the proposed approach when compared to existing methods.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com