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Under the applied reactions conditions, all the carbon-based materials are apparently stable in the first 15 h time on stream.
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A significant discrepancy with respect to obtained sizes and applied reaction conditions can be noted.
The stability, recoverability and reusability of the designed nanocatalyst were also studied under applied reaction conditions.
For the hot injection methodology, a significant discrepancy with respect to obtained sizes and applied reaction conditions is reported.
The obtained kinetic constants for benzene hydroxylation by Aae APO cannot be regarded as simply "apparent" with the applied reaction setup.
Under the applied reaction conditions (200 °C, 50 bar total pressure) only nitrites and molecular nitrogen were detected as primary products.
Under the applied reaction conditions (190 °C, 50 bar total pressure) in the presence of heterogeneous β-MnO2-supported catalysts, formate and ammonium ions were detected as primary products.
The catalytic formulations elaborated in this work were shown to be stable under the applied reaction conditions without any significant leaching of the active phase.
Based on the applied reaction model, the (bio-) physical pathways can be unravelled by globally analysing time-resolved experimental data.
No radiochemical incorporation was observed regardless of the conditions applied (reaction temperature, reaction time, solvent, synthon).
The backward reaction (reverse WGSR) was neglected owing to the low conversion and the large distance from the equilibrium under the applied reaction conditions.
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