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In anhydrous state at 150 °C, the highest proton conductivity measured was 0.002 S/cm for PVA:PAMPS 1,2,4-triazole (1:1:1) comPAMPS 1,2,4-triazole
Maximum proton conductivity of PVBC-ATET-TA2.5 was found to be 0.01 S/cm at 150 °C in the anhydrous state.
However the resultant product was more crystalline and transformed on heating to the anhydrous state with markedly reduced onset temperature with lower energy surfaces than powders produced from larger sized starting material.
Both PILs demonstrated Tg below 0 °C, bulk ionic conductivities in anhydrous state in the range of 8.4 × 10−7-1.5 × 10−5 S/cm (25 °C) and electrochemical stability of 3.1 3.4 V (25 °C).
In the anhydrous state, the proton conductivity of PVTriTA100 is 2.2 × 10−4 S/cm at 150 °C and that of PVTriTA150 is approximately 0.012 S/cm at 80 °C which is similar to that of hydrated Nafion®.
Calcium chloride, a well-known desiccant that has a propensity to absorb water into its crystal lattice, was selected as non-infrared active substrate to accentuate the efficacy of the cell in preserving the anhydrous state of the sample by straightforward monitoring of the water bands.
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The concept of the DOD HTFSI complexes was applied to a polybase, poly[p-phenylene-2,5- 1,3,4-oxadiazole)] (poly[p-phenylene-2,5- 1,3,4-oxadiazoleof the poly[p-phenylene-2,5- 1,3,4-oxadiazole a view to realizing anhydrous solid-state fast poly[p-phenylene-2,5- 1,3,4-oxadiazole
The thermal curve for pure FA has a typical sharp endothermic melting at about 172.7 °C, indicative of its anhydrous and crystalline state, while that of phospholipids exhibit a minor endothermal peak at 231.7 248.6 °C.
It can be prepared only under the anhydrous conditions by solid-state reactions at temperatures above ~1300 °C, e.g., by heating homogenized equimolar quantities of DCPA and CaCO3 in dry air, or in a flow of dry nitrogen (Elliott 1994, 1998; Kai et al. 2009).
General synthesis : All reactions were carried out under an inert atmosphere with dry solvents under anhydrous conditions, unless otherwise stated.
In a related but as yet little-explored avenue, proton conducting organic ionic plastic crystals offer the potential advantage of providing a solid state matrix for anhydrous proton conductivity.
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