The scoring system heavily favours regular bond angles, prefers to add new atoms in less congested orientations, and encourages avoidance of certain types of impossible structures.
As further evidence of this, the angle of approach of the nucleophile (N2−C2=O angle) ranges from 68° to 92°, whereas an angle of 107° (the Bürgi−Dunitz angle) is preferred for nucleophilic attack at a carbonyl (29).
Both are eager to stay on message, burnishing egos while advancing the angle they prefer.
And there are, of course, two typing positions, depending on the angle you prefer to look at.
The aluminum oxide walls, the 45° spherical-cap window and the 45° wall- angle receiver are preferred due to their best compromise between thermal efficiency and wall temperature.
The crystallographic orientations developed were correlated with the change in the cathodic overpotential, the angle between the preferred oriented plane and the lowest energy of formation plane (0 0 0 2), and the pulse electrodeposition parameters.
In fingerprint authentication systems, inclusion of more features increase matching scores and hence the angle information is preferred.
Fans will be able to direct their own games, choosing the camera angles they prefer, as soccer fans can do now in England on Rupert Murdoch's BSkyB channel.
A sensitivity analysis shows that hydraulic fracture (HF) tend to be arrested by a natural fracture (HF) under low approach angles and prefer to cross the NF under higher in-situ differential stress states.
We sought to establish a regional glaucoma physician collaborative to evaluate and improve adherence to the American Academy of Ophthalmology's Primary Open-angle Glaucoma (POAG) Preferred Practice Pattern (PPP) guidelines.
These commercial preparations revealed preferred angles of diffraction by means of characteristic arrays of dot (Fig. 6J L) which could not be distinguished in the patterns obtained for NLP or NB (Fig. 6A I).
