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The phrase "and when free" is correct and usable in written English.
It can be used to indicate a condition or time when someone is available or unoccupied.
Example: "Please call me and when free, we can discuss the project further."
Alternatives: "and when available" or "and when you have time".
Exact(9)
Toomer circled around left end, and when free safety Kwamie Lassiter stood in front of him at the Arizona 10-yard line, Toomer stopped, faked and then slipped into the end zone untouched.
In the second study, Lee et al.4 resolved the crystal structure of β-klotho's extracellular domain when bound to and when free from FGF21, in the absence of FGFRs.
And when free speech warriors are called out for their actions they lash out.
We've seen problems and anomalies arise around this sort of thing before - for instance, when the funding of English students diverged from Scotland's, when water boards were privatised but not in Scotland, and when free personal care in Scotland didn't align with the UK-wide attendance allowance.
The conversation now (including the ongoing one in the comments section of my previous post) revolves around whether Kelly's points about the promotion of obesity were justified, if and when free speech should be censored, and the conflicting messages in the media about weight and body images.
And when free trade drives down wages, it can do so industry-wide, region-wide, or even nationwide, so its victims are impossible to pinpoint.
Similar(51)
The experimental results correlated well with theory when the forced and free convections were in the same direction (assisting flow) and when free-convection mass transfer dominated the mass-transfer process.
And when free-market advocacy alone hasn't worked, military force and brutal repression are always at hand to cow the public, all in the interest of promoting the privatization of public resources, the shredding of the social safety net and opening up new markets for foreign investors.
The electromagnet would return to its starting point and when freed to move along the wire again, the recording would be replayed.
Blacks were — and are — more likely to be suspended from school, denied parole and when freed from prison denied benefits, kept out of public housing, blocked from employment or professional licenses and, once again, prevented from voting.
It also explains why children pay special attention to the activities and conversations of older children and adults and why, when free to do so, they ask never-ending questions about what is going on.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com