ancillary ligands

USAGE SUMMARY

The phrase "ancillary ligands" is correct and usable in written English.
It is typically used in scientific contexts, particularly in chemistry and biochemistry, to refer to ligands that support or enhance the function of a primary ligand in a complex. Example: "The study focused on the role of ancillary ligands in stabilizing the metal center of the coordination complex."

✓ Grammatically correct

Science

Human-verified examples from authoritative sources

Exact Expressions

60 human-written examples

Furthermore, the role of the bulky ancillary ligands has been analysed.

Polymer

The central metal ions are coordinated in N2O4 and N4O2 fashions depending on the ancillary ligands.

Inorganica Chimica Acta

Thus, latent complexes can be designed using different amines as ancillary ligands.

Journal of Molecular Catalysis A: Chemical

Ancillary ligands and metal cations significantly influence the structure of the complexes.

Journal of Solid State Chemistry

The effect of the ancillary ligands on their electronic structures, DNA-binding affinities and spectra was revealed.

Journal of Molecular Structure: THEOCHEM

So it may be able to control the interaction between the complex and DNA-base-pairs via varying ancillary ligands.

Journal of Molecular Structure: THEOCHEM

The structures exhibit different dimensionality depending on the nature of the metal ions and/or the ancillary ligands.

Inorganica Chimica Acta

The central metal ions are coordinated in N2O4, N4O2, N2O3 and N3O3 fashions, depending on the ancillary ligands.

Polyhedron

More importantly, coordination in acyl oxygen atoms and ancillary ligands (bpe) as monodentate decorating ligands in 4 are rarely reported.

Journal of Solid State Chemistry

The central metal ions are coordinated in N2O5, N2O4, NO4 and N3O fashions, depending on the center metals and the ancillary ligands.

Polyhedron

This study provided a new method for further improving and tuning the ECL efficiency by designing new iridium complexes with the appropriate cyclometalated or ancillary ligands.

Journal of Organometallic Chemistry

Expert writing Tips

Best practice

When writing about coordination complexes, be precise in distinguishing between primary ligands and "ancillary ligands" to clarify their respective roles in the complex's function and stability.

Common error

Avoid assuming that "ancillary ligands" are always inert or passive. They can significantly influence the electronic and steric properties of the metal center, affecting the complex's reactivity and selectivity.

Linguistic Context

The phrase "ancillary ligands" functions as a noun phrase that includes an adjective ("ancillary") modifying the noun ("ligands"). This phrase typically identifies a set of molecules or ions that bind to a central metal atom, providing support or modification to the primary ligand. Ludwig AI confirms this is a valid and usable English phrase.

Expression frequency: Very common

Frequent in

Science

100%

Less common in

News & Media

0%

Formal & Business

0%

Encyclopedias

0%

Ludwig's WRAP-UP

In summary, "ancillary ligands" refers to supporting molecules in chemical complexes, playing a crucial role in influencing the properties of the central metal atom. Ludwig AI validates this phrase as correct and commonly used, particularly in scientific contexts. The phrase is most frequently found in scientific literature, indicating a formal and technical register. When discussing coordination complexes, differentiating between primary and "ancillary ligands" ensures clarity in describing their respective functions. Common synonyms include "supporting ligands" and "auxiliary ligands".

More alternative expressions

Phrases that express similar concepts, ordered by semantic similarity:

supporting ligands

Replaces "ancillary" with a more common synonym, focusing on the supporting role of the ligands.

auxiliary ligands

Uses "auxiliary" as a synonym for "ancillary", highlighting the supplementary function of the ligands.

stabilizing ligands

Emphasizes the role of the ligands in maintaining the stability of the complex.

secondary ligands

Emphasizes the ligands' role as being secondary to the primary ligand in the complex.

co-ligands

Highlights the cooperative role of these ligands alongside the primary ligand.

enhancing ligands

Focuses on the ligands' function in improving or boosting the characteristics of the complex.

helper ligands

An informal alternative that describes ligands assisting the primary ligand.

modifying ligands

Highlights the ability of the ligands to change or adjust the properties of the primary ligand or complex.

non-participating ligands

Describes ligands that do not directly participate in the main reaction but support the complex.

spectator ligands

An alternative that suggests these ligands are present but not directly involved in the core process.

FAQs

What is the role of "ancillary ligands" in a metal complex?

Ancillary ligands support the primary ligand by influencing the electronic and steric environment around the metal center, thereby affecting the complex's stability, reactivity, and selectivity.

What are some synonyms for "ancillary ligands"?

Alternatives include "supporting ligands", "auxiliary ligands", or "secondary ligands", depending on the specific context.

How do "ancillary ligands" affect the properties of a coordination complex?

Ancillary ligands can modify the electronic structure, DNA-binding affinities, and spectra of the complex. Their steric bulk can also influence reaction rates and selectivity.

Can the choice of "ancillary ligands" be used to tune the properties of a metal complex?

Yes, varying the "ancillary ligands" is a common strategy for tuning the electronic, optical, and catalytic properties of metal complexes. This allows for the design of complexes with specific desired characteristics.