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This substrate had the highest analytical enhancement factor (6.73 × 106).
However, these substrates demonstrated a moderate analytical enhancement [42] averaged over the probe laser beam spot.
The analytical enhancement factors of these substrates are on the order of (1 3) × 104, and uniform SERS signals are obtained over large areas.
Analytical enhancement factor (AEF) of Au substrates between 105 and 106 and limits of detection (LOD) of TMPyP ∼5 × 10−8 M were determined.
The analytical enhancement factor was accordingly increased from 1.8 × 105 for Ag/TiO2 NPA up to 7.8 × 105 for Ag/TiO2 NRA.
The analytical enhancement factor (AEF) values at 10−6 M R6G were respectively 6.2 × 103 and 1.3 × 104 for the flat TiN film and wrinkly TiN film.
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To compare between the analytical enhancements [42] provided by the SERS structures formed, we used the rhodamine 6G (R6G) dye as a test analyte.
Of course, the analytical SERS enhancement coefficients attained with our structures are a few orders of magnitude lower than those for such structures as the silver-immobilized nanorod assembly [41, 42].
All other things being equal, the analytical integral SERS enhancement of the GNR-OPC substrates is higher than that of the thick, randomly oriented GNR assemblies on plain silicon wafers.
Explicit analytical expressions for the enhancement factors and concentration profiles of the gaseous solutes are derived.
The analytical results predict the enhancement of the quantum tunneling effect as the oxide thickness is reduced.
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