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Two microliter samples were analyzed on a 2.1 × 100 mm ACQUITY™ 1.7 μm BEH C18 column (Waters, Milford, MA, USA), which was maintained at 40°C using an Waters ACQUITY™ UPLC system.
EIMS and HRTOF-EIMS data were acquired on an Waters Auto Spec Premierp 776 spectrometer (America, Waters).
The analysis of the l- and d, l-FDLA (mixture of d- and l-FDLA) derivatives was performed using an Waters Sunfire C18 column (4.6*150 mm, 5 μm) maintained at 30 °C.
Final extracts were analysed using an Waters Acquity UPLC system coupled to a Quattro Premier XE mass spectrometer equipped with an electrospray interface operated in both positive and negative ionization mode.
UPLC/MS/MS analyses were carried out on an Waters Xevo TQ MS ACQUITY UPLC system (Waters, MA).
Chromatographic separation was performed on an Waters symmetry shield™RP10 (4.6 mm × 250 mm, 5.0 um, Milford, MA, USA) column maintained at 30°C.
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