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"an extensive chapter" is correct and usable in written English
You can use it to refer to a section of a book, paper or other work that is particularly long or detailed. For example, "The book contains an extensive chapter on the history of the United States."
Exact(3)
And yet as I read, I found myself imagining that Montagu's letters — written between 1709 and her death in 1762 — formed an extensive chapter within Ms. Lessing's novel, which is itself made up of letters and bureaucratic reports from an Earth-like world called Shikasta.
Argyle (2002) is a reference book in social psychology with an extensive chapter on the GHQ measure and another one on unemployment.
His first manuscript of Mysterium contained an extensive chapter reconciling heliocentrism with biblical passages that seemed to support geocentrism.
Similar(57)
He calls these "presentational suggestives" (Vorstellungssuggestive) and devotes a very extensive chapter of his main work to the treatment of them.
Marshall's input into what became known as the Copeland Report amounted to three extensive chapters of a two volume, 1,677-page work.
Its problem is that these directors have saddled themselves with extensive chapters of the old choreography.
Fitzgerald's revisions included an extensive rewriting of Chapter VI and VIII.
She includes detailed maps, prints and photographs and adds an extensive bibliography after each chapter.
In this chapter, an extensive overview on the surface modification methods has been discussed to develop antimicrobial polymeric biomaterials.
In this chapter an extensive list of the various methods of removal of cyanide, phenol, ammonia, and chemical oxygen demand from coke wastewater is given along with the key advancements of the application of membrane.
The introduction provides a road map to the entire book and ends with an appendix, answers to problems from each of the chapters, an extensive list of references, and author and subject index, resulting in a 734 page treatise.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com