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The phrase "amassed a substantial collection" is correct and usable in written English.
You can use it when describing the gathering or accumulation of a significant number of items, such as books, art, or collectibles.
Example: "Over the years, she has amassed a substantial collection of rare stamps from around the world."
Alternatives: "gathered a significant collection" or "accumulated a large collection."
Exact(4)
Ms. White and Mr. Levy amassed a substantial collection of classical art over several decades.
A prominent couturier, philanthropist, connoisseur and bibliophile, Doucet (1853-1929) first amassed a substantial collection of 18th-century paintings and furniture.
And over the years, it amassed a substantial collection of original illustration work, by members like Norman Rockwell and Charles Dana Gibson, that could be seen more easily after the society opened its gallery in 1981.
My professional and personal life is such that I have amassed a substantial collection of documents, voice recordings, photographs, and other digital flotsam.
Similar(56)
In later years he also amassed a significant collection of old-master works on paper.
In the nineteenth century and for most of the twentieth, the major collectors were European, then American; in the seventies, the Japanese market for violins exploded, with the Nippon Foundation, in Tokyo, amassing a substantial collection, including the famous quartet assembled by Niccolò Paganini.
It is a notable coup for this prolific director who has amassed a substantial reputation in Europe.
Beyond that, Gardner hasn't amassed a substantial record on civil liberties and national security issues in the House.
This field has amassed a substantial amount of quantitative data, on which mathematical models have developed.
And while others collected dolls, Ms. Dunne amassed a modest collection of vintage perfume bottles.
He amassed a great collection of books, which would form the nucleus of the Laurentian Library.
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Since I tried Ludwig back in 2017, I have been constantly using it in both editing and translation. Ever since, I suggest it to my translators at ProSciEditing.

Justyna Jupowicz-Kozak
CEO of Professional Science Editing for Scientists @ prosciediting.com