"although ironically" is a correct and usable phrase in written English.
It is typically used to introduce a contrast or contradiction between two ideas or situations. Here is an example: "Although ironically, the politician who promised to cut taxes for the middle class ended up raising them instead." In this example, the use of "although ironically" indicates that the politician's actions are unexpected or contradictory to their previous promises.
"Although, ironically, my daughter's nine and she's the last person in her class who can ride a bike.
Responding to the inevitable gap between corporate rhetoric and action requires significant emotional labour, although ironically the outcome may be that emotions need to be deliberately left aside.
Although ironically the closer South Africa get the bigger their choke and therefore the more likely they are to stuff it up instead.
While an MP3 can travel around the globe within hours of release, tapes inhabit the cloistered world of the true underground – although, ironically, most are sold online.
He identifies a preoccupation among the region's writers with "bloody death" that reaches back to ancient myth, although ironically these countries are among the safest in Europe.
Likewise I benefitted from additional daylight in week 2, although ironically it's so gloomy today that I had to turn on all the lights in my office just to get my solar calculator to work.
Although defeated – ironically by three of the set-pieces at which they are supposed to excel – he believes the second-half performance showed the world the Potters' new craft: "You've seen how the Arsenals and Swanseas are accustomed to playing that type of football.
Since the income of PIKs depended solely on school fees, the problems of curriculum overloading and inappropriate teaching appeared to be more serious among these schools, although these, ironically, made PIKs more popular among parents.
The Oscars cannot be approached ironically (although James Franco certainly tried).
Ironically, although talent and drive may not be inherited, vocal quality often is.
Ironically, although the SNP stood outside the convention, it has been a significant beneficiary of devolution.
